Format

Send to

Choose Destination
Angew Chem Int Ed Engl. 2012 Apr 2;51(14):3414-7. doi: 10.1002/anie.201107816. Epub 2012 Feb 28.

Carbon(sp(3))-fluorine bond-forming reductive elimination from palladium(IV) complexes.

Author information

1
Department of Chemistry, University of Michigan, Ann Arbor, 48109, USA.

Abstract

Pd(IV)-fluoride complexes, some of which are remarkably insensitive to water, have been synthesized and used in the title reaction, which proceeds with high selectivity to give the product of the C(sp(3))-F coupling. Preliminary mechanistic studies implicate a pathway involving dissociation of pyridine followed by direct C-F coupling at the Pd center.

PMID:
22374779
DOI:
10.1002/anie.201107816
Free full text

Supplemental Content

Full text links

Icon for Wiley Icon for MLibrary (Deep Blue)
Loading ...
Support Center