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Dalton Trans. 2012 Apr 14;41(14):4195-8. doi: 10.1039/c2dt11891b. Epub 2012 Feb 7.

Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels.

Author information

1
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

Abstract

The dynamics of oligo(vinylidene fluoride) (OVDF) confined in regular nanochannels of a porous coordination polymer (PCP) was studied by means of dielectric spectroscopy. The OVDF chains in the PCP nanopores showed two Arrhenius-type relaxation processes at lower temperatures than the relaxation temperature observed for the neat OVDF, showing the enhanced mobility of the confined OVDF.

PMID:
22310907
DOI:
10.1039/c2dt11891b

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