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Angew Chem Int Ed Engl. 2012 Mar 12;51(11):2623-7. doi: 10.1002/anie.201107070. Epub 2012 Jan 3.

Lattice expansion of highly oriented 2D phthalocyanine covalent organic framework films.

Author information

1
Department of Chemistry and Chemical Biology, Cornell University, Baker Laboratory, Ithaca, NY 14853, USA.

Abstract

Expanding into application: covalent organic framework (COF) films are ideally suited for vertical charge transport and serve as precursors of ordered heterojunctions. Their pores, however, were previously too small to accommodate continuous networks of complementary electron acceptors. Four phthalocyanine COFs with increased pore size well into the mesoporous regime are now described.

PMID:
22223402
DOI:
10.1002/anie.201107070

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