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Dalton Trans. 2012 Apr 7;41(13):3630-2. doi: 10.1039/c1dt11740h. Epub 2011 Nov 17.

Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers.

Author information

1
University of Bielefeld, Inorganic and Structural Chemistry, Germany.

Abstract

The first gas phase structure of a silanetriol, tert-butylsilane-triol [(t)BuSi(OH)(3)], determined by gas electron diffraction (GED), is reported. Quantum chemical calculations have been performed to elucidate potential intermolecular interactions between silanetriol molecules in the gas phase. The results are set into contrast to solid state structures of (t)BuSi(OH)(3) and related compounds.

PMID:
22089403
DOI:
10.1039/c1dt11740h

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