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Org Lett. 2011 Dec 16;13(24):6436-9. doi: 10.1021/ol202728v. Epub 2011 Nov 15.

Gram-scale synthesis of the A'B'-subunit of angelmicin B.

Author information

1
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Abstract

A gram-scale enantiospecific synthesis of the A'B'-subunit of angelmicin B is reported. The synthesis involves a Lewis acid catalyzed contrasteric Diels-Alder reaction and a tandem silyl zincate 1,6-addition/enolate oxidation sequence.

PMID:
22084899
PMCID:
PMC3237735
DOI:
10.1021/ol202728v
[Indexed for MEDLINE]
Free PMC Article

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