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Chem Commun (Camb). 2012 Jan 4;48(1):154-6. doi: 10.1039/c1cc14396d. Epub 2011 Oct 31.

Pyridine encapsulated hyperbranched polymers as mimetic models of haeme containing proteins, that also provide interesting and unusual porphyrin-ligand geometries.

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1
Department of Chemistry, The University of Sheffield, Sheffield, S3 7HF, UK. l.j.twyman@sheffield.ac.uk

Abstract

This communication describes the use of non-covalent chemistry to construct recyclable porphyrin cored HBPs. The non-covalent design allows the polymeric backbone to be rescued and reused after porphyrin degradation. The steric environment within the polymeric encapsulated ligand notably affected the porphyrin coordination geometry.

PMID:
22039580
DOI:
10.1039/c1cc14396d
[Indexed for MEDLINE]
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