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Chem Commun (Camb). 2011 Dec 21;47(47):12694-6. doi: 10.1039/c1cc15525c. Epub 2011 Oct 31.

In situ high pressure study of ZIF-8 by FTIR spectroscopy.

Author information

1
Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada.

Abstract

ZIF-8 as a promising storage material was investigated at high pressures up to ~39 GPa by in situ FTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression.

PMID:
22037659
DOI:
10.1039/c1cc15525c

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