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J Org Chem. 2011 Nov 18;76(22):9452-9. doi: 10.1021/jo201849j. Epub 2011 Oct 18.

One-pot synthesis of chiral nonracemic amines.

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1
School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK.

Abstract

One-pot five-component reactions of oxathiazolidine-S-oxides with mesitylmagnesium bromide, lithium bis(trimethylsilyl)amide, aldehydes and Grignard reagents afford chiral nonracemic amines or sulfinamides in good yields and high stereoselectivities.

PMID:
21992680
DOI:
10.1021/jo201849j
[Indexed for MEDLINE]
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