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Angew Chem Int Ed Engl. 2011 Oct 10;50(42):9903-6. doi: 10.1002/anie.201103616. Epub 2011 Sep 16.

[Mn(bipyridyl)(CO)3Br]: an abundant metal carbonyl complex as efficient electrocatalyst for CO2 reduction.

Author information

1
Université Joseph Fourier-Grenoble1/CNRS, Département de Chimie Moléculaire UMR, Laboratoire de Chimie Inorganique Redox, Institut de Chimie Moléculaire de Grenoble FR-CNRS, France.

Abstract

Manganese at work: carbonyl bipyridyl complexes based on manganese, a non-noble abundant and inexpensive metal, have been proved to be excellent molecular catalysts for the selective electrochemical reduction of CO(2) to CO under mild conditions. Another advantage of manganese complexes over rhenium complexes is that these catalysts operate at markedly less overpotential (0.40 V gain).

PMID:
21922614
DOI:
10.1002/anie.201103616
[Indexed for MEDLINE]

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