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J Colloid Interface Sci. 2011 Dec 1;364(1):49-55. doi: 10.1016/j.jcis.2011.08.025. Epub 2011 Aug 22.

Effect of γ-irradiation on the growth of ZnO nanorod films for photocatalytic disinfection of contaminated water.

Author information

1
Facultad de Ciencias, Universidad Nacional de Ingeniería, P.O. Box 31-139, Av. Túpac Amaru 210, Lima, Peru.

Abstract

The growth of ZnO nanorods on a flat substrate containing γ-irradiated seeds and their ability to photocatalytically eliminate bacteria in water were studied. The seed layer was obtained, by the spray pyrolysis technique, from zinc acetate solutions γ-irradiated within the range from 0 to 100 kGy. Subsequently, to grow the rods, the seeds were immersed in a basic solution of zinc nitrate maintained at 90 °C. The rate of crystal growth on the seed layer during the thermal bath treatment was kept constant. The resulting materials were characterized morphologically by scanning electron and atomic force microscopies; X-ray diffraction was used to study their morphology and structure and ultraviolet-visible spectroscopy to determine their absorbance. The obtained seed films were morphologically dependent on the radiation dose and this was correlated with the ZnO nanorod films which presented a texture in the (002) direction perpendicular to the substrate. The rods have a hexagonal mean cross section between 20 and 140 nm. Using these rods, the photocatalytic degradation of Escherichia coli bacteria in water was studied; a positive influence of the crystalline texture on the degradation rate was observed.

PMID:
21906749
DOI:
10.1016/j.jcis.2011.08.025
[Indexed for MEDLINE]

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