Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes

Chem Commun (Camb). 2011 Oct 14;47(38):10614-6. doi: 10.1039/c1cc14165a. Epub 2011 Aug 30.

Abstract

The first examples of thiazol-5-ylidene complexes featuring group 9, 10 and 11 metal centers, have been prepared by deprotonation of a series of 2,3,4-triaryl-susbtituted thiazolium salts in the presence of the corresponding transition metal precursor.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Coordination Complexes / chemical synthesis
  • Coordination Complexes / chemistry*
  • Crystallography, X-Ray
  • Isomerism
  • Ligands
  • Molecular Conformation
  • Rhodium / chemistry
  • Thiazoles / chemistry*
  • Transition Elements / chemistry*

Substances

  • Coordination Complexes
  • Ligands
  • Thiazoles
  • Transition Elements
  • Rhodium