Correlation interferometry is a particular application of Fourier transform spectroscopy with partially scanned interferograms. Basically, it is a technique to obtain the difference between the spectra of atmospheric radiance at two diverse spectral resolutions. Although the technique could be exploited to design an appropriate correlation interferometer, in this paper we are concerned with the analytical aspects of the method and its application to high-spectral-resolution infrared observations in order to separate the emission of a given atmospheric gas from a spectral signal dominated by surface emission, such as in the case of satellite spectrometers operated in the nadir looking mode. The tool will be used to address some basic questions concerning the vertical spatial resolution of H2O and to develop an algorithm to retrieve the columnar amount of CO2. An application to complete interferograms from the Infrared Atmospheric Sounding Interferometer will be presented and discussed. For H2O, we have concluded that the vertical spatial resolution in the lower troposphere mostly depends on broad features associated with the spectrum, whereas for CO2, we have derived a technique capable of retrieving a CO2 columnar amount with accuracy of ≈±7 parts per million by volume at the level of each single field of view.