Abstract
Experimental and computational experiments show that the electrophile MeS(+) attacks a single Fe center in Fe(2)(propanedithiolate)(CO)(4)(PMe(3))(2) followed by isomerization of this terminal thiolato complex to the corresponding μ-SMe derivative.
This journal is © The Royal Society of Chemistry 2011
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Catalytic Domain
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Coordination Complexes / chemistry*
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Crystallography, X-Ray
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Ferric Compounds / chemistry
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Hydrogenase / chemistry
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Iron-Sulfur Proteins / chemistry
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Molecular Conformation
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Stereoisomerism
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Sulfhydryl Compounds / chemistry
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Thermodynamics
Substances
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Coordination Complexes
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Ferric Compounds
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Iron-Sulfur Proteins
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Sulfhydryl Compounds
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dithiol-iron(III)-sulfide complex
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iron hydrogenase
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Hydrogenase