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Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8157-60. doi: 10.1002/anie.201103192. Epub 2011 Jul 12.

Nucleophilic aromatic substitution reactions of 1,2-dihydro-1,2-azaborine.

Author information

1
Department of Chemistry, University of Oregon, Eugene, 97403-1253, USA.

Abstract

Could go either way: the addition of nucleophiles to the parent 1,2-dihydro-1,2-azaborine and subsequent quenching with an electrophile generates novel substituted 1,2-azaborine derivatives. Mechanistic studies are consistent with two distinct nucleophilic aromatic substitution pathways depending on the nature of the nucleophile.

PMID:
21751320
PMCID:
PMC3437382
DOI:
10.1002/anie.201103192
[Indexed for MEDLINE]
Free PMC Article

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