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Angew Chem Int Ed Engl. 2011 Aug 22;50(35):8082-5. doi: 10.1002/anie.201102651. Epub 2011 Jul 12.

Mechanically driven reorganization of thermoresponsive diblock copolymer assemblies in water.

Author information

1
Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, Australia.

Abstract

Controlled formation of a variety of 3D structures was observed at high polymer weight fractions in water from a single diblock, consisting of poly(N-isopropylacrylamide), PNIPAM, and polystyrene, PSTY segments. The structures form through a mechanical process driven by swelling of hydrophilic polymer segments upon a change in temperature.

PMID:
21751314
DOI:
10.1002/anie.201102651

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