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Chem Commun (Camb). 2011 Aug 21;47(31):8976-8. doi: 10.1039/c1cc13516c. Epub 2011 Jul 5.

Copper-catalyzed N-arylation of amines with part-per-million catalyst loadings under air at room temperature.

Author information

1
Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, PR China.

Abstract

An efficient copper-catalyzed method for N-arylation of amines has been developed with part-per-million catalyst loadings at room temperature under air. Reactions of substituted (E)-1-(2-halophenyl)alkanone oximes with aliphatic amines or aromatic amines provided the N-arylation products in good to excellent yields.

PMID:
21727962
DOI:
10.1039/c1cc13516c
[Indexed for MEDLINE]

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