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Org Lett. 2011 Aug 5;13(15):3826-9. doi: 10.1021/ol201316z. Epub 2011 Jun 30.

Organocatalytic asymmetric Strecker reaction of di- and trifluoromethyl ketoimines. Remarkable fluorine effect.

Author information

1
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, PR China.

Abstract

A highly enantioselective Strecker reaction of difluoromethyl and trifluoromethyl ketoimines was developed. Remarkable fluorine effect on the reactivity and selectivity is observed and discussed.

PMID:
21718056
DOI:
10.1021/ol201316z

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