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J Biomol NMR. 2011 Jul;50(3):277-84. doi: 10.1007/s10858-011-9516-2. Epub 2011 Jun 11.

Chemical shift correlation at high MAS frequencies employing low-power symmetry-based mixing schemes.

Author information

1
Department of Physics, Ubon Ratchathani University, Thailand. cherbst@fli-leibniz.de

Abstract

An approach for conveniently implementing low-power CN ( n ) (ν) and RN ( n ) (ν) symmetry-based band-selective mixing sequences for generating homo- and heteronuclear chemical shift correlation NMR spectra of low γ nuclei in biological solids is demonstrated. Efficient magnetisation transfer characteristics are achieved by selecting appropriate symmetries requiring the application of basic RF elements of relatively long duration and numerically tailoring the RF field modulation profile of the basic element. The efficacy of the approach is experimentally shown by the acquisition of (15)N-(13)C dipolar and (13)C-(13)C scalar and dipolar coupling mediated chemical shift correlation spectra at representative MAS frequencies.

PMID:
21674236
DOI:
10.1007/s10858-011-9516-2
[Indexed for MEDLINE]

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