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Chem Commun (Camb). 2011 Aug 21;47(31):8919-21. doi: 10.1039/c1cc12460a. Epub 2011 Jun 10.

Selective gas sorption in a [2+3] 'propeller' cage crystal.

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1
Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK.

Abstract

A [2+3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.

PMID:
21666905
DOI:
10.1039/c1cc12460a
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