Synthesis of terpolymers by click reactions

Chem Asian J. 2011 Oct 4;6(10):2584-91. doi: 10.1002/asia.201100138. Epub 2011 May 18.

Abstract

Well-defined polymeric structures were easily generated through living polymerization systems, in particular, living radical polymerizations. The polymeric precursors with orthogonal functionalities were subsequently clicked together with single or double (combinatorial) click reactions, such as the copper-catalyzed azide-alkyne cycloadditions (CuAAC) and Diels-Alder reactions, to create a wide variety of linear and nonlinear terpolymers.

Publication types

  • Review

MeSH terms

  • Alkynes / chemistry
  • Azides / chemistry
  • Catalysis
  • Click Chemistry*
  • Copper / chemistry
  • Cyclization
  • Molecular Structure
  • Polymers / chemical synthesis*
  • Polymers / chemistry

Substances

  • Alkynes
  • Azides
  • Polymers
  • Copper