Diethyl 2-amino-5-[(E)-(furan-2-yl-methyl-idene)amino]-thio-phene-3,4-di-carboxyl-ate

Stéphane Dufresne; W G Skene

doi:10.1107/S1600536810043746

Diethyl 2-amino-5-[(E)-(furan-2-yl-methyl-idene)amino]-thio-phene-3,4-di-carboxyl-ate

Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):o3027. doi: 10.1107/S1600536810043746.

Authors

Stéphane Dufresne¹, W G Skene

Affiliation

¹ Department of Chemistry, University of Montreal, CP 6128, succ. Centre-ville, Montréal, Québec, Canada H3C 3J7.

Abstract

In the crystal structure of the title compound, C(15)H(16)N(2)O(5)S, the azomethine adopts the E configuration. The two heterocyclic rings adopt an anti-periplanar orientation. The mean planes of the thio-phene and furan rings are twisted by 2.51 (4)°. The crystal structure exhibits inter-molecular N-H⋯O hydrogen bonding. π-π stacking is also observed, the centroid-to-centroid distance being 3.770 (4) Å.