Tetra-imidazole-bis(trichloro-acetato)copper(II)

Acta Crystallogr Sect E Struct Rep Online. 2010 May 22;66(Pt 6):m682. doi: 10.1107/S1600536810017459.

Abstract

The title compound, [Cu(C(2)Cl(3)O(2))(2)(C(3)H(4)N(2))(4)], was prepared by the reaction of imidazole and trichloro-acetatocopper(II). The Cu(II) atom adopts a distorted octa-hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl-ate O atoms of two trichloro-acetate anions. The mol-ecular structure and packing are stabilized by N-H⋯O hydrogen-bonding inter-actions. Close inter-molecular Cl⋯Cl contacts [3.498 (3) Å] are also found in the structure.