Format

Send to

Choose Destination
Phys Chem Chem Phys. 2011 Aug 28;13(32):14283-92. doi: 10.1039/c1cp20700h. Epub 2011 May 9.

Covalent networks through on-surface chemistry in ultra-high vacuum: state-of-the-art and recent developments.

Author information

1
CNRS, CEMES, Nanosciences Group, 29 rue Jeanne Marvig, 31055 Toulouse, France. gourdon@cemes.fr

Abstract

The fabrication of large molecular devices, directly on surfaces in UHV conditions, by covalent coupling of smaller precursors has become in the past years an attractive solution for Molecular Electronics. This review presents the state-of-the-art and an analysis of the potential of this new field, from Ullmann type C-C coupling, cyclodehydrogenation, and reactions involving heteroelements to 2D polymerisation on insulating thin films. Mechanistic insights are also mentioned, giving preliminary explanations on the influence of the substrate and the 2D confinement. Potential perspectives for further developments are then evoked.

PMID:
21552604
DOI:
10.1039/c1cp20700h

Supplemental Content

Full text links

Icon for Royal Society of Chemistry
Loading ...
Support Center