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Chem Commun (Camb). 2011 Jun 14;47(22):6338-40. doi: 10.1039/c1cc11437a. Epub 2011 May 6.

The Diels-Alder reaction of C60 and cyclopentadiene in mesoporous silica as a reaction medium.

Author information

1
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan. minakata@chem.eng.osaka-u.ac.jp

Abstract

As a new organic reaction medium, a periodic mesoporous inorganic material was found to function as a "solid solvent" in a Diels-Alder reaction of C(60) with cyclopentadiene. This finding was supported by a concentration effect and a kinetic study of the reaction.

PMID:
21547291
DOI:
10.1039/c1cc11437a

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