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Chem Commun (Camb). 2011 May 28;47(20):5750-2. doi: 10.1039/c1cc11487e. Epub 2011 Apr 18.

Surfactant-free synthesis of palladium nanoclusters for their use in catalytic cross-coupling reactions.

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1
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka 564-8680, Japan.

Abstract

Surfactant-free Pd nanoclusters (Pd NCs) (size: 1-1.5 nm) showed high catalytic activity in the Suzuki-Miyaura cross-coupling and Mizoroki-Heck reactions. The Pd NCs had a high turnover number, up to 6.0 × 10(8), which can be recycled at least five times without loss of catalytic activity.

PMID:
21503284
DOI:
10.1039/c1cc11487e
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