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ACS Nano. 2011 Apr 26;5(4):2787-94. doi: 10.1021/nn200195k. Epub 2011 Apr 8.

Nanographene-constructed carbon nanofibers grown on graphene sheets by chemical vapor deposition: high-performance anode materials for lithium ion batteries.

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Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China.


We report on the fabrication of 3D carbonaceous material composed of 1D carbon nanofibers (CNF) grown on 2D graphene sheets (GNS) via a CVD approach in a fluidized bed reactor. Nanographene-constructed carbon nanofibers contain many cavities, open tips, and graphene platelets with edges exposed, providing more extra space for Li(+) storage. More interestingly, nanochannels consisting of graphene platelets arrange almost perpendicularly to the fiber axis, which is favorable for lithium ion diffusion from different orientations. In addition, 3D interconnected architectures facilitate the collection and transport of electrons during the cycling process. As a result, the CNF/GNS hybrid material shows high reversible capacity (667 mAh/g), high-rate performance, and cycling stability, which is superior to those of pure graphene, natural graphite, and carbon nanotubes. The simple CVD approach offers a new pathway for large-scale production of novel hybrid carbon materials for energy storage.


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