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J Am Chem Soc. 2011 Mar 23;133(11):3780-3. doi: 10.1021/ja111670s. Epub 2011 Feb 28.

Rh(NHC)-catalyzed direct and selective arylation of quinolines at the 8-position.

Author information

1
Department of Chemistry and Molecular Level Interface Research Center, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea.

Abstract

A new catalytic protocol for the regioselective direct arylation of quinoline derivatives at the 8-position has been developed. The reaction is catalyzed by a Rh(NHC) system, and the choice of the NHC ligand was most important for achieving high reactivity and selectivity.

PMID:
21355550
DOI:
10.1021/ja111670s

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