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Org Lett. 2011 Mar 18;13(6):1447-9. doi: 10.1021/ol200135m. Epub 2011 Feb 14.

Novel aerobic oxidation of primary sulfones to carboxylic acids.

Author information

1
Department of Chemistry, Allegheny College, Meadville, Pennsylvania 16335, United States.

Abstract

Primary alkyl aryl sulfones are converted to the corresponding carboxylic acids in fair to excellent yield through double deprotonation and exposure to atmospheric oxygen. The methodology allows for the convenient synthesis of (13)C labeled carboxylic acids.

PMID:
21319833
DOI:
10.1021/ol200135m
[Indexed for MEDLINE]

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