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Dalton Trans. 2011 Mar 28;40(12):2703-6. doi: 10.1039/c0dt01588a. Epub 2011 Feb 9.

New high-nuclearity manganese clusters containing mixed chelating ligands: syntheses, crystal structures and magnetochemical characterization.

Author information

1
State Key Laboratory of Coordinate Chemistry, School of Chemistry and Chemical Engineering, Nanjing Nantional Laboratory of Microstructures, Nanjing University, P. R. China.

Abstract

Two polynuclear mixed-valence manganese clusters, [Mn(13)] and [Mn(16)], containing mixed chelating ligands were synthesized and structurally characterized. The alternating current (AC) susceptibilities of both complexes reveal nonzero frequency-dependent out-of-phase (χ(M)'') signals.

PMID:
21308119
DOI:
10.1039/c0dt01588a

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