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Chem Soc Rev. 2011 Apr;40(4):1875-84. doi: 10.1039/c0cs00099j. Epub 2011 Jan 17.

C-H oxidation by platinum group metal oxo or peroxo species.

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1
Department of Chemistry, Yale University, New Haven, CT 06520, USA. meng.zhou@yale.edu

Abstract

While C-H oxidation by ruthenium oxo compounds has been broadly applied in organic synthesis, examples of C-H oxidation by metal oxo complexes from the rest of the platinum group are still rare. We survey the preparation and reactivity of these late-transition metal oxo and peroxo complexes in this tutorial review.

PMID:
21240429
DOI:
10.1039/c0cs00099j

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