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Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 7;64(Pt 7):m880. doi: 10.1107/S1600536808016590.

1-(4-Chloro-phen-yl)piperazine-1,4-diium tetra-chlorido-zincate(II) monohydrate.

Abstract

In the crystal structure of the title compound, (C(10)H(15)ClN(2))[ZnCl(4)]·H(2)O, the Zn atom is coordinated by four Cl atoms in a tetrahedral geometry. The water mol-ecules and the 1-(4-chloro-phen-yl)piperazine-1,4-diium cations inter-act with the [ZnCl(4)](2-) anions through O-H⋯Cl, N-H⋯Cl, N-H⋯O and C-H⋯Cl hydrogen bonds (five simple and one bifurcated). Inter-molecular π-π stacking inter-actions are present between adjacent aromatic rings of 1-(4-chloro-phenyl)-piperazine-1,4-diium cations (the centroid-centroid distance is 3.453 Å).

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