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Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):o416. doi: 10.1107/S160053680800024X.

4-Amino-phenyl-sulfur penta-fluoride.

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  • 1Department of Inorganic Chemistry and Technology, Jozef Stefan Institute, Jamova 39 1000 Ljubljana, Slovenia.


In the title compound, C(6)H(6)F(5)NS, the environment of the S atom is roughly octa-hedral. The axial F-S bond appears slightly elongated with respect to the four equatorial F-S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane by 0.154 (4) Å. The F-S-C-C torsion angles differ greatly from the values observed in the related structure of 4-acetamido-phenyl-sulfur penta-fluoride. The packing is stabil-ized by weak N-H⋯F contacts.

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