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Chem Commun (Camb). 2011 Feb 7;47(5):1455-7. doi: 10.1039/c0cc04807k. Epub 2010 Dec 2.

Toward the synthesis of sequence-controlled vinyl copolymers.

Author information

1
Department of Chemical Engineering, Tsinghua University, Beijing 100084, China.

Abstract

An ATRA based strategy to synthesize vinyl copolymers with monomer-level sequence control is proposed. In each cycle, one allyl alcohol is added to the ATRP chain end, and then the hydroxymethyl residue is oxidized to carboxylic acid and a side group is introduced via esterification, making the new chain end active for the next cycle.

PMID:
21125120
DOI:
10.1039/c0cc04807k

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