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J Am Chem Soc. 2010 Oct 6;132(39):13636-8. doi: 10.1021/ja105640p.

Autoprogrammed synthesis of triple-layered Au@Pd@Pt core-shell nanoparticles consisting of a Au@Pd bimetallic core and nanoporous Pt shell.

Author information

1
World Premier International Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan.

Abstract

Here we report an autoprogrammed synthesis of unique Au@Pd@Pt triple-layered core-shell structured nanoparticles consisting of a Au core, Pd inner layer, and nanoporous Pt outer shell. The proposed synthesis rationally utilizes the temporal separations of the depositions of Au, Pd, and Pt which affords spontaneously step-by-step formation of triple-layered core-shell colloids. The proposed one-step method is unique in its simplicity and is a significant finding for the facile creation of multilayered nanoarchitectures with designed compositions and desired functions.

PMID:
20831169
DOI:
10.1021/ja105640p

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