Send to

Choose Destination
See comment in PubMed Commons below
J Am Chem Soc. 2010 Jun 30;132(25):8548-9. doi: 10.1021/ja1031997.

Deformations in Si-Li anodes upon electrochemical alloying in nano-confined space.

Author information

School of Materials Science and Engineering, Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.


The energy density of Li-ion batteries can be increased if graphitic anodes are replaced with nanostructured Si-based materials. Design of efficient Si anodes requires a better fundamental understanding of the possible changes in Si-Li alloy morphology during cycling. Here we propose a simple elastoplastic model to predict morphological changes in Si upon electrochemical reaction with Li in a confined geometry, such as a pore of a carbon nanotube (CNT). Our experiments with CNTs having inner Si coatings of different thicknesses confirmed the theoretical predictions and demonstrated irreversible shape changes in the first cycle and fully reversible shape changes in subsequent cycles. During the first lithiation, Si was found to adapt to the restricted shape of the rigid CNT pore and plastically deform during electrochemical alloying with Li. The sequential Li insertion and extraction periodically alters the tube size between the expanded and contracted states. The produced samples of porous Si with rigid CNT outer shell showed capacity up to 2100 mAh/g, stable performance for over 250 cycles, and outstanding average Coulombic efficiency in excess of 99.9%. CNT walls were demonstrated to withstand stresses caused by the initial Si expansion and Li intercalation.

PubMed Commons home

PubMed Commons

How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Support Center