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Chem Commun (Camb). 2010 Jul 14;46(26):4668-79. doi: 10.1039/c0cc00563k. Epub 2010 May 26.

Glycosylation with glycosyl N-phenyltrifluoroacetimidates (PTFAI) and a perspective of the future development of new glycosylation methods.

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1
State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China. byu@mail.sioc.ac.cn

Abstract

The glycosyl N-phenyltrifluoroacetimidates (PTFAI) have within the last ten years been applied in the synthesis of a wide variety of the oligosaccharides and glycoconjugates. Especially, these donors are found advantageous in glycosidic coupling with 'arming' sugar donors, ketose donors, and with less nucleophilic acceptors. A comprehensive review of the PTFAI donors is provided in a hope to reflect from a particular angle the current status and future trend of the glycosylation chemistry.

PMID:
20502836
DOI:
10.1039/c0cc00563k
[Indexed for MEDLINE]
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