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Chem Commun (Camb). 2010 Jul 7;46(25):4466-8. doi: 10.1039/c001483d. Epub 2010 May 20.

Unusual magnetic properties of a two-coordinate heteroleptic linear cobalt(II) complex.

Author information

1
Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA.

Abstract

The synthesis and characterization of two-coordinate cobalt(ii) complexes CoAr'(2) (1) and Ar'CoN(SiMe(3))(2) (2) (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6-(i)Pr(2))(2)) are reported. The magnetic data for 2 show that it has an unexpectedly high mu(eff) of 5.65 mu(B) whereas the bent complex 1 has a significantly lower moment.

PMID:
20490404
DOI:
10.1039/c001483d
[Indexed for MEDLINE]

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