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J Am Chem Soc. 2010 May 26;132(20):6920-2. doi: 10.1021/ja101586w.

Metalloradical-catalyzed aliphatic carbon-carbon activation of cyclooctane.

Author information

1
Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, The People's Republic of China.

Abstract

The aliphatic carbon-carbon activation of c-octane was achieved via the addition of Rh(ttp)H to give Rh(ttp)(n-octyl) in good yield under mild reaction conditions. The aliphatic carbon-carbon activation was Rh(II)(ttp)-catalyzed and was very sensitive to porphyrin sterics.

PMID:
20441175
DOI:
10.1021/ja101586w

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