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Phys Chem Chem Phys. 2010 Apr 21;12(15):3653-5. doi: 10.1039/b925741a. Epub 2010 Mar 10.

Direct measurement of vertical binding energy of a hydrated electron.

Author information

1
Japan Science and Technology Agency, CREST, Sanbancho, Chiyoda-ku, Tokyo 102-0075, Japan.

Abstract

We present the first measurement of the vertical binding energy (VBE) of a hydrated electron in bulk water by the time-resolved photoelectron spectroscopy (TRPES) of the charge-transfer-to-solvent (CTTS) reaction in aqueous NaI solution. Our best estimate of VBE is 3.27 +/- 0.10 eV for H(2)O and 3.20 +/- 0.10 eV for D(2)O.

PMID:
20358061
DOI:
10.1039/b925741a

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