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ACS Nano. 2010 Feb 23;4(2):1099-107. doi: 10.1021/nn9012934.

Microstructure and properties of well-ordered multiferroic Pb(Zr,Ti)O(3)/CoFe(2)O(4) nanocomposites.

Author information

1
Max Planck Institute of Microstructure Physics, D-06120 Halle, Germany. gaoxingsen@gmail.com

Abstract

A nanofabrication technique combining pulsed laser deposition and a nanoporous anodic aluminum oxide membrane mask is being proposed to prepare various types of multiferroic nanocomposites, viz. periodically ordered CoFe(2)O(4) dots covered by a continuous Pb(Zr,Ti)O(3) layer, Pb(Zr,Ti)O(3) dots covered with CoFe(2)O(4), and Pb(Zr,Ti)O(3)/CoFe(2)O(4) bilayer heterostructure dots. By properly tuning the processing parameters, epitaxial nanodot-matrix composites can be obtained. For the composite consisting of CoFe(2)O(4) nanostructures covered by a Pb(Zr,Ti)O(3) film, an unexpected out-of-plane magnetic easy axis induced by the top Pb(Zr,Ti)O(3) layer and a uniform microdomain structure can be observed. The nanocomposites tested by piezoresponse force microscopy (PFM) exhibit strong piezoelectric signals, and they also display magnetoelectric coupling revealed by magnetic-field dependent capacitance measurement.

PMID:
20112922
DOI:
10.1021/nn9012934

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