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J Am Chem Soc. 2010 Feb 17;132(6):1774-5. doi: 10.1021/ja910126s.

Systematic cross-linking changes within a self-assembled monolayer in a nanogap junction: a tool for investigating the intermolecular electronic coupling.

Author information

1
The Department of Chemical Engineering and Russell Berrie Nanotechnology Institute, Technion-Israel Institute of Technology, Haifa 32000, Israel.

Abstract

Here, we show that a controllable cross-linking within a self-assembled monolayer can be used as a tool for investigating the (lateral) intermolecular coupling between adjacent organic molecules. We draw this conclusion based on macroscopic electrical experiments with self-assembled hexyltrichlorosilane (HTS) having different degrees of Si-O-Si intermolecular bonds in a planar nanogap junction.

PMID:
20088587
DOI:
10.1021/ja910126s

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