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J Chem Phys. 2009 Oct 28;131(16):161107. doi: 10.1063/1.3257600.

Observation of buried water molecules in phospholipid membranes by surface sum-frequency generation spectroscopy.

Author information

1
FOM Institute for Atomic and Molecular Physics, Sciencepark 104, 1098XG Amsterdam, The Netherlands.

Erratum in

  • J Chem Phys. 2010 Dec 14;133(22):229901.

Abstract

We investigate the structure and orientation of water molecules at the water-lipid interface, using vibrational sum-frequency generation in conjunction with a maximum entropy phase retrieval method. We find that interfacial water molecules have an orientation opposite to that predicted by electrostatics and thus are likely localized between the lipid headgroup and its apolar alkyl chain. This type of water molecule is observed for phospholipids but not for structurally simpler surfactants.

PMID:
19894919
DOI:
10.1063/1.3257600
[Indexed for MEDLINE]

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