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Chem Commun (Camb). 2009 Nov 14;(42):6487-9. doi: 10.1039/b911905a. Epub 2009 Sep 14.

Sp-sp(3) C-C bond formation via Fe(OTf)(3)/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols.

Author information

1
State Key Laboratory of Natural and Biomimetic Drugs, Peking University, School of Pharmaceutical Sciences, Peking University, Xue Yuan Rd. 38, Beijing 100191, China.

Abstract

An Fe(OTf)(3)/TfOH cocatalyzed sp-sp(3) C-C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H(2)O is the sole by-product.

PMID:
19841818
DOI:
10.1039/b911905a
[Indexed for MEDLINE]

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