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J Am Chem Soc. 2009 Nov 11;131(44):16042-4. doi: 10.1021/ja9075327.

Polymerization of enantiopure monomers using syndiospecific catalysts: a new approach to sequence control in polymer synthesis.

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1
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, 14853-1301, USA.

Abstract

The ring-opening polymerization of a mixture of enantiomerically pure but different monomers using an yttrium complex as initiator proceeds readily at room temperature to give the corresponding highly alternating polyester.

PMID:
19835375
DOI:
10.1021/ja9075327
[Indexed for MEDLINE]
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