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Chem Commun (Camb). 2009 Oct 7;(37):5558-60. doi: 10.1039/b909561f. Epub 2009 Aug 20.

Two diamino-substituted lithiocarbanions in one molecule.

Author information

1
Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstrasse 15, 33615 Bielefeld, Germany.

Abstract

tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.

PMID:
19753356
DOI:
10.1039/b909561f

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