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Org Lett. 2009 Oct 15;11(20):4492-5. doi: 10.1021/ol901519k.

Rapid assembly of vinigrol's unique carbocyclic skeleton.

Author information

1
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Abstract

Detailed in this account are our efforts toward the total synthesis of vinigrol. A highly expedient and convergent synthetic approach made possible by the use of a strategic oxidative dearomatization reaction coupled with a series of ensuing substrate controlled transformations is discussed.

PMID:
19728692
PMCID:
PMC2759413
DOI:
10.1021/ol901519k
[Indexed for MEDLINE]
Free PMC Article

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