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Chem Commun (Camb). 2009 Aug 14;(30):4521-3. doi: 10.1039/b910410k. Epub 2009 Jul 6.

Phosphinidene group-transfer with a phospha-Wittig reagent: a new entry to transition metal phosphorus multiple bonds.

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1
Department of Chemistry and the Molecular Structure Center, Indiana University Bloomington, IN 47405, USA.

Abstract

The phosphanylidene-sigma(4)-phosphorane reagents Me(3)P[double bond, length as m-dash]PAr (Ar = 2,4,6-(t)Bu(3)C(6)H(2) and 2,6-Mes(2)C(6)H(3)) are good delivery vehicles of the terminal phosphinidene moiety, PAr, to early-transition metals composed of zirconium and vanadium.

PMID:
19617970
DOI:
10.1039/b910410k
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