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Magn Reson Chem. 2009 Nov;47(11):989-93. doi: 10.1002/mrc.2482.

New tricyclic and tetracyclic pyranocoumarins with an unprecedented C-4 substituent. Structure elucidation of tamanolide, tamanolide D and tamanolide P from Calophyllum inophyllum of French Polynesia.

Author information

1
Laboratoire de Biodiversité Terrestre et Marine, Université de Polynésie Française, BP 6570, 98702 Faaa, Tahiti, Polynésie française.

Abstract

Three new pyranocoumarin derivatives, tamanolide (1), tamanolide D (2) and tamanolide P (3), were isolated from the almond seeds of Calophyllum inophyllum L. (Clusiaceae) grown in French Polynesia. These compounds, having an unprecedented C-4 isobutyl substituent, have been characterized as a new class of pyranocoumarins called tamanolides. Their structures were elucidated on the basis of 1D and 2D NMR techniques (COSY, NOESY, HSQC and HMBC) in association with MS (HR-ESI-MS) data analysis.

PMID:
19603395
DOI:
10.1002/mrc.2482
[Indexed for MEDLINE]

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