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Org Lett. 2009 Aug 6;11(15):3322-5. doi: 10.1021/ol901064p.

Cobalt-catalyzed 1,4-hydrovinylation of styrenes and 1-aryl-1,3-butadienes.

Author information

1
Fachbereich Chemie, Philipps-Universit├Ąt Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany. hilt@chemie.uni-marburg.de

Abstract

The application of aryl-substituted starting materials such as styrene and 1-aryl-substituted 1,3-butadiene derivatives in the cobalt-catalyzed 1,4-hydrovinylation reaction has been investigated. The use of unsymmetrical alpha,omega-dienes in the hydrovinylation with 1-aryl-1,3-butadiene led chemoselectively to the 1:1 or the 1:2 adducts depending on the stoichiometry of the starting materials.

PMID:
19583205
DOI:
10.1021/ol901064p

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