This work intercompared two Bi-directional Reflectance Distribution Function (BRDF) models, the modified Minnaert's model and the RossThick-LiSparse-R model, in the estimation of the directional emissivity in Middle Infra-Red (MIR) channel from the data acquired by the Spinning Enhanced Visible and Infra-Red Imager (SEVIRI) onboard the first Meteosat Second Generation (MSG1). The bi-directional reflectances in SEVIRI channel 4 (3.9 microm) were estimated from the combined MIR and Thermal Infra-Red (TIR) data and then were used to estimate the directional emissivity in this channel with aid of the BRDF models. The results show that: (1) Both models can relatively well describe the non-Lambertian reflective behavior of land surfaces in SEVIRI channel 4; (2) The RossThick-LiSparse-R model is better than the modified Minnaert's model in modeling the bi-directional reflectances, and the directional emissivities modeled by the modified Minnaert's model are always lower than the ones obtained by the RossThick-LiSparse-R model with averaged emissivity differences of approximately 0.01 and approximately 0.04 over the vegetated and bare areas, respectively. The use of the RossThick-LiSparse-R model in the estimation of the directional emissivity in MIR channel is recommended.